Muscovite Research Articles

Alteration mineralogy, characteristics and shortwave infrared spectroscopy of white mica in the Zijinshan ore field, Fujian Province: Implications for porphyry Cu prospecting

Alteration mineralogy, characteristics and shortwave infrared spectroscopy of white mica in the Zijinshan ore field, Fujian Province: Implications for porphyry Cu prospecting

The Val Biandino Intrusive Suite (central Southern Alps, N Italy): new geochronological and geochemical data on the Early Permian magmatic activity in the Southalpine Domain

The Early Permian in the present-day Europe area was a time when a major tectonic shift occurred, leading from the tectonic collapse of the Variscan orogeny to the crustal extension and thinning that characterized the Early Permian times. Crustal extension was associated with extensive magmatism at different crustal levels: from gabbro in the lower crust or at the mantle/crust transition to subaerial high-SiO2 volcanic activity. In the whole Southalpine Domain, the Early Permian intrusive bodies occur from the west (e.g. Ivrea-Verbano Complex and “Graniti dei Laghi”) to the east (Ifinger, Brixen and Cima d’Asta intrusive complexes). Among these, in the central Southern Alps (comprised between the Giudicarie Belt and the Lake Como), minor intrusive complexes also occur. The Val Biandino Intrusive Suite consists of two magmatic units: the Val Biandino Quartz-Diorite (VBQD) and the Valle di San Biagio Granite (VSBG). The first of them consists of gabbro-diorite to granodiorite bodies associated with leucocratic cordierite-bearing granitic dikes that intruded the pre-Permian basement. To the west, a W-dipping normal fault of Permian age represents the boundary between this unit and the Valle di San Biagio porphyric granite. All rock varieties of the Val Biandino Intrusive Suite display a high-K calc-alkaline affinity with metaluminous to peraluminous character. Field crosscutting relationships point to a late generation of the cordierite granites of the Val Biandino Quartz-Diorite unit with respect to the more mafic types. SHRIMP U–Pb zircon dating provided an age of 285.2 ± 1.9 Ma for a cordierite granite of the Val Biandino Quartz-Diorite unit and 283.2 ± 1.9 Ma for the porphyric Valle di San Biagio Granite. Geochemical data suggest that gabbro-diorite, quartz-diorite, granodiorite and leucogranite are not co-magmatic. The existing gaps in term of SiO2 wt% and the higher HREE contents in mafic and intermediate rocks with respect to granite coupled with similar LREE in all rocks support this hypothesis. The high Rb/Sr ratios (> 1) in leucogranite, together with the occurrence of white mica and cordierite point to a significant contribution of crustal partial melting in their genesis. The Val Biandino Intrusive Suite was likely formed through the interaction of magma genesis at the mantle/crust transition and partial melting of the heterogeneous pre-Permian basement of the Southalpine Domain. This scenario explains the strong heterogeneity displayed by the relatively small intrusive complex and the strong crustal signature exhibited by all the magmatic types of the Val Biandino Intrusive Suite.

Room-Temperature Ferroelectric Epitaxial Nanowire Arrays with Photoluminescence.

The development of large-scale, high-quality ferroelectric semiconductor nanowire arrays with interesting light-emitting properties can address limitations in traditional wide-bandgap ferroelectrics, thus serving as building blocks for innovative device architectures and next-generation high-density optoelectronics. Here, we investigate the optical properties of ferroelectric CsGeX3 (X = Br, I) halide perovskite nanowires that are epitaxially grown on muscovite mica substrates by vapor phase deposition. Detailed structural characterizations reveal an incommensurate heteroepitaxial relationship with the mica substrate. Furthermore, photoluminescence that can be tuned from yellow-green to red emissions by varying the halide composition demonstrates that these nanowire networks can serve as platforms for future optoelectronic applications. In addition, the room-temperature ferroelectricity and ferroelectric domain structures of these nanowires are characterized using second harmonic generation (SHG) polarimetry. The combination of room-temperature ferroelectricity with photoluminescence in these nanowire arrays unlocks new avenues for the design of novel multifunctional materials.

Reassessing the timing of high-strain deformation in the Strangways Metamorphic Complex, Central Australia, by in situ mica Rb–Sr and titanite U–Pb geochronology

Dating the timing of deformation within shear zones is critical to quantifying orogenic processes and developing time-resolved regional tectonic frameworks. Such work requires the integration of detailed microstructural analysis with in situ geochronology to quantify when deformation mechanisms were active at the micro-scale. The Proterozoic, granulite-facies Strangways Metamorphic Complex was exhumed during the Devonian to Carboniferous intracontinental Alice Springs Orogeny. New microstructural observations, quartz c -axis orientation analyses, mica chemistry, Ti-in-biotite thermometry, in situ mica Rb–Sr and titanite U–Pb geochronology outline a detailed history of ductile shearing across the complex. Movement along the north boundary shear zone of Strangways Metamorphic Complex appears to have initiated c. 382 Ma, preceding peak metamorphism in the area during the Alice Springs Orogeny. Widespread reverse-sense ductile shearing occurred within the Strangways Metamorphic Complex between c. 365 and 355 Ma, and correlates with rapid cooling of the region. Late-stage ductile deformation is recorded at c. 335 Ma, likely reflecting the terminal exhumation of the Strangways Metamorphic Complex. Finally, the new in situ muscovite and biotite Rb–Sr data collected herein permit comparison with previous two-point mica Rb–Sr isochrons and 40 Ar– 39 Ar dates from the same specimens. In the rocks analysed, the biotite Rb–Sr system returned dates similar to the previous 40 Ar– 39 Ar white mica dates, perhaps indicating a similar effective closure temperature. Supplementary material: Test results and previous geochronology data from the Alice Springs Orogeny are available in tabular form at https://osf.io/yjp24/?view_only=0bf5bec9f5c94a1aa4fb413320ec24e8

U–Pb LA-ICP-MS and Re–Os dating of wolframite and molybdenite: Constraints on multiple mineralization and cooling history (40Ar/39Ar) for the magmatic–hydrothermal system at Borralha, northern Portugal

The Borralha area (Iberian Massif, Portugal) reflects a long-lived and multiphase magmatism (ca. 316 to 300 Ma), characterized by three types of granite emplacement during two different extensional events (E1 and E2) and one compressional event (C3) within the Variscan orogeny. The W (Cu) mineralization styles correspond to veinlets and quartz veins (i.e., São António and Santa Helena), and disseminations in the Santa Helena breccia pipe. Molybdenite coexists with an Fe-bearing wolframite–quartz assemblage in the Venise breccia pipe and quartz veins (i.e., São José and São Paulo).The geochemistry and geochronology of wolframite and molybdenite samples were studied by electron probe microanalysis (EPMA), in-situ U–Pb laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS) and Re–Os thermal ionization mass spectrometry (TIMS). The wolframite yields a U–Pb age (sample WBV1) of 315.2 ± 4.7 Ma (2σ), representing the first recognized episode of W deposition in the Iberian Massif. Wolframite samples (WBV1, WB1, and WB4) have a ferberite composition with a hübnerite/ferberite ratio of < 29. High amounts of Nb (up to 3703 ppm) with low Ta (up to 123 ppm) and REEs (up to 11.4 ppm) and conversely, low amounts of Nb (up to 471 ppm) with high Ta (up to 190 ppm) and REEs (up to 53.7 ppm) were measured in wolframite samples. The REEs normalized patterns of the wolframite samples record a mixed signature. Large and positive Eu/Eu* and Er/Er* anomalies were identified (sample WBV1), whereas negative Ce/Ce* and Nd/Nd* anomalies were observed in samples WB1 and WB4.Molybdenite Re–Os dating yields absolute ages ranging from 305.1 to 303.8 ± 2.2 Ma (2σ), which are coeval with the emplacement of E2 biotite granite (Penedos; I-type; <305 Ma). Low amounts of Re (<1 ppm), W, Co, Ni, As, Cu, Bi, Fe, Mn V and Se (<0.005 wt%) were detected in the molybdenite structure.Constraints between the timing of W- and Mo-deposition and a protracted cooling history of the host rocks are confirmed by 40Ar/39Ar white mica dating. The 40Ar/39Ar ages obtained for secondary white micas collected from Mo veins (Venise breccia pipe; 277 ± 3 and 287 ± 4 Ma 2σ) and W (Cu) dissemination (Santa Helena breccia pipe; 287 ± 2 and 279.0 ± 6 Ma 2σ) record the isotopic resetting by later hydrothermal overprints and cooling /exhumation history after E2 Gerês biotitic granite emplacement.The W-ore deposition did occurred during the final E1 extensional tectonic stage (315 Ma) and E2 extensional tectonic stage for Mo-ore deposition, where a temporal offset was needed for the adjustment of tectonic conditions after the C3 compressional and E2 extensional stage started.

Metamorphic evolution of sillimanite gneiss in the high-pressure terrane of the Western Gneiss Region (Norway)

Abstract. Sillimanite-bearing gneisses in the Romsdal region of the Western Gneiss Region (south Norway) have been investigated to document the presence, formation, composition and petrological evolution of the sillimanite-bearing assemblages. Sillimanite is found in augen gneiss, as nodular gneiss, and in well-foliated sillimanite–mica gneiss. Lenses and layers of eclogite occur within the gneiss units. The sillimanite-bearing gneisses are heterogranular and dominated by quartz, plagioclase (An29–41), K-feldspar and biotite (Mg# = 0.48–0.58; Ti = 0.16–0.36 a.p.f.u.), with variable amounts of white mica (Si = 6.1–6.3). K-feldspar occurs as porphyroclasts in augen gneiss, and garnet constitutes resorbed porphyroblasts. Garnet (Alm46–56Sps24–36Prp10−20Grs4–6; Mg# = 0.22–0.29) shows rimward-decreasing Mg#, together with a smaller grossular decrease and a marked spessartine increase up to Sps36. The foliation is defined by crystal-preferred-orientation micas, elongation of shape-preferred-orientation coarse K-feldspar phenocrysts and a modal banding of phases. Sillimanite occurs as coarse orientation-parallel matrix porphyroblasts, as finer grains and as fibrolitic aggregates. Quartz constitutes coarser elongated grains and monomineralic rods. Pseudosection modelling suggests that the peak-metamorphic mineral assemblage of garnet–sillimanite–feldspar–biotite–quartz–ilmenite–liquid equilibrated at temperatures up to 750 °C and pressures of 0.6 GPa. Subsequent retrogression consumed garnet. Mineral replacement and melt crystallization involved sillimanite, white mica, K-feldspar and quartz. The results document a metamorphic retrogression of the sillimanite gneisses in accordance with the presence of remnants of eclogites and high-pressure granulites in this northwestern part of the Western Gneiss Region.

The application of PRISMA hyperspectral satellite imagery in the delineation of distinct hydrothermal alteration zones in the Chilean Andes: The Marimaca IOCG and the Río Blanco-Los Bronces Cu-Mo porphyry districts

This study provides an overview of the application of hyperspectral imagery acquired by the Italian satellite mission “PRecursore IperSpettrale della Missione Applicativa” (PRISMA), for mapping hydrothermal and supergene mineral alteration zones associated with different Cu deposits in the Chilean Andes. Study areas include the Marimaca Copper Project in the Naguayán district (Antofagasta Province), hosting Late Jurassic – Early Cretaceous iron oxide-copper–gold mineralizations and the Río Blanco-Los Bronces district (Santiago Region) known for its Late Miocene – Early Pliocene copper-molybdenum porphyry deposits. These mineral systems exhibit hydrothermal alteration haloes extending over several kilometers, with upward and outward mineral zonation.To characterize the surface-exposed alteration, the satellite imagery was processed using a multiple feature extraction workflow targeting the relative abundances and compositions of specific supergene and hydrothermal alteration minerals, including Fe-oxides and hydroxides (hematite-goethite), phyllosilicates (micas-kaolinite-chlorite), hydroxyl-bearing sulfates (alunite-natroalunite-jarosite) and epidote. The results reveal a zonation from proximal sulfates (natroalunite to alunite) and Al-rich white mica (ranging from 0.3 km-wide for the area identified to the east of the Marimaca deposit to 1 km-wide in correspondence of the Los Sulfatos deposit, respectively) to distal Al-poor white mica (0.2 to 0.5 km-wide, respectively) and an outer chlorite-epidote zone. In the Marimaca Project area, the structurally-controlled alteration evolves west to east from chlorite-rich to phengitic white mica (Al-poor). A NNE-SSW trending supergene leached cap covers a 6 km-long and up to 2 km-wide area from north to south. Our study documents how spaceborne hyperspectral imaging spectroscopy can support mineral exploration by enabling non-invasive reconnaissance mapping of the outcropping rocks, providing specific targeting information for follow-up field surveys and drilling campaigns.

Late Cretaceous Tectono-Metamorphic Events in the Skyros Upper Metamorphic Unit (Olympus Mountain), Aegean Sea, Greece

Late Cretaceous metamorphic events are known in Crete and the Cyclades from klippen above the External Hellenides. This work extends their occurrence to the North Aegean area within the tectonic units of the Internal Hellenides. New 40Ar/39Ar white mica ages from garnet-bearing micaschists of the Upper Metamorphic Unit of Skyros Island, cropping out in the Skyrian Olympus Mountain, document a Late Cretaceous tectono-metamorphic evolution. Several mica generations have been distinguished using electron probe microanalyses and were dated using the 40Ar/39Ar method: a relict mica older than 96 Ma, followed by a foliation-forming mica of about 88–84 Ma and alteration phases ≤ 68 Ma were recognized. This Cretaceous tectono-metamorphic evolution falls between the closure of the internal Axios/Vardar oceanic basin in the Late Jurassic–Early Cretaceous, and the closure of the external Pindos–Cyclades oceanic basin in the Early Cenozoic. The position of the Upper Metamorphic Unit of Skyros was probably within the evolving Hellenic volcanic/magmatic arc during the continuous subduction of the African plate beneath the European plate. The present tectonic position of the units bearing the Late Cretaceous metamorphic event is the result of the Cenozoic tectonic emplacement onto the more external units across the Hellenides from the Pelagonian to the Pindos–Cyclades domain.

Tectonic Evolution of the Condrey Mountain Schist: An Intact Record of Late Jurassic to Early Cretaceous Franciscan Subduction and Underplating

AbstractThe Klamath Mountains in northern California and southern Oregon are thought to record 200+ m.y. of subduction and terrane accretion, whereas the outboard Franciscan Complex records ocean‐continent subduction along the North American margin. Unraveling the Klamath Mountains' Late Jurassic history could help constrain this transition in subduction style. Key is the Mesozoic Condrey Mountain Schist (CMS), comprising, in part, a subduction complex that occupies a structural window through older, overlying central Klamath thrust sheets but with otherwise uncertain relationships to more outboard Klamath or Franciscan terranes. The CMS consists of two units (upper and lower), which could be correlated with (a) other Klamath terranes, (b) the Franciscan, or (c) neither based on regional structures and limited extant age data. Upper CMS protolith and metamorphic dates overlap with other Klamath terranes, but the lower CMS remains enigmatic. We used multiple geochronometers to constrain the timing of lower CMS deposition and metamorphism. Maximum depositional ages (MDAs) derived from detrital zircon geochronology of metasedimentary rocks are 153–135 Ma. Metamorphic ages from white mica K‐Ar and Rb‐Sr multi‐mineral isochrons from intercalated and coherently deformed metamafic lenses are 133–116 Ma. Lower CMS MDAs (&lt;153 Ma) predominantly postdate other Klamath terrane ages, but subduction metamorphism appears to start before the earliest coherent Franciscan underplating (ca. 123 Ma). The lower CMS thus occupies a spatial and temporal position between the Klamath Mountains and Franciscan and preserves a non‐retrogressed record of the Franciscan Complex's early history (&gt;123 Ma), otherwise only partially preserved in retrogressed Franciscan high grade blocks.

A multi-proxy detrital study from Permian-Triassic fluvial sequences of Victoria Land (Antarctica): Implications for the Gondwanan basin evolution

One of the most complete Permian-Triassic fluvial sequences of the Beacon Supergroup, characterizing the infilling of the Transantarctic Basin, is recorded in the Allan Hills in Victoria Land (Antarctica). The multidisciplinary provenance approach carried out in this study includes UPb analysis on detrital zircons, chemistry on detrital mineral phases (garnet and white mica), and sandstone petrography. These, coupled with the data regarding the stratigraphic/sedimentological framework, provide a reconstruction of the geological history of the Permian-Triassic portion of the Beacon Supergroup, showing shifting clastic provenance from different source rocks. Results obtained from this integrated study support a source for the Permian Weller Coal Measures from the local basement, made up of very low- to high grade metamorphic rocks. A compositional shift is recorded with the Lower Triassic Feather Conglomerate, mainly linked with changes in the fluvial style, likely associated with tectonic activity. The Middle to Upper Triassic Lashly Formation shows the main provenance change, supporting a distal source region: the fluvial system received a volcanoclastic input derived from the Permian-Triassic arc located to the east of the basin. The compositional and provenance variations, together with paleocurrent indicators, compared to the coeval units in the central Transantarctic Mountains, allow the reconstruction of the basin evolution and of the changing clastic drainage patterns. Data support the occurrence of articulated sub-basins where alluvial sedimentation settled, in which a morphological-structural divide was represented by the Ross High, separating during the Permian up to the Early Triassic the Victoria Land sub-basin from the main Transantarctic Basin. According to the changed composition of the Lashly Formation sandstones, it appears that in the Middle/Late Triassic, the Ross High was not more a morphological barrier, and that the Victoria Land sub-basin was joined with the Transantarctic foreland Basin.

A Graphene‐Mica‐Based Photo‐Thermal Actuator for Small‐Scale Soft Robots

AbstractSmall‐scale soft robots demonstrate intricate life‐like behavior and allow navigation through arduous terrains and confined spaces. However, the primary challenges in soft robotics are 1) creating actuators capable of quick, reversible 22D‐to‐3D shape morphing with adjustable stiffness, 2) improving actuation force and robustness for wider applications, and 3) designing holistic systems for untethered manipulation and flexible multimodality in practical scenarios. Here, mechanically compliant paper‐like robots are presented with multiple functionalities. The robots are based on photothermally activated polymer bimorph actuators that incorporate graphene for the photo‐thermal conversion of energy and muscovite mica, with its high Young's modulus, providing the required stiffness. Conversion of light into heat leads to thermal expansion and bending of the stress‐mismatched structures. The actuators are designed on the basis of a modified Timoshenko model, and numerical simulations are employed to evaluate their actuation performance. The membranes can be utilized for light‐driven programmable shape‐morphing. Localized control allows the implementation of active hinges at arbitrary positions within the membrane. Integrated into small‐scale soft robots in mass production, the membrane facilitates locomotion, rolling, and flipping of the robots. Further, grasping and kicking mechanisms are demonstrated, highlighting the potential of such actuators for future applications.

Coupled U–Pb and 40Ar/39Ar chronology of late‐stage intrusions at Elba Island (Italy) supports late Miocene long‐lived magma reservoirs in the Tyrrhenian upper crust

AbstractThe late Miocene Monte Capanne and Porto Azzurro plutons are investigated by means of coupled U–Pb zircon and 40Ar/39Ar white mica dating to test the occurrence of long‐lived magmatic systems in the upper crust. Zircon crystallized for &gt;1 Ma in both plutonic systems, with supersolidus conditions overlapping for ~220 ka indicating previously unrecognized co‐existence of the two reservoirs. The development of the Porto Azzurro high T‐aureole is post‐dated by continuous igneous zircon crystallization until ~6.0 Ma. By linking crystallization to post‐emplacement cooling of late‐stage pulses in both western and eastern Elba we constrain long‐lived sizeable reservoirs (possibly the same reservoir) in the Tyrrhenian upper crust between ~8 and 6 Ma.

Petrography study of the recent sediments in Hareer’s region at Basrah Governorate - Southern Iraq

Two sites of Hareer’s region is located in the southern part of Iraq, specifically in the northern Basrah Governorate. The sites are at a depth of 5 meters. The results of heavy mineral analysis showed that there are fifteen types include; Opaque grain (Iron Oxide), Chlorite, Muscovite mica, Biotite, Orthopyroxene, Clinopyroxene, Amphibole (Hornblende and Actinolite), Epidote, Garnet, Kyanite, Staurolite, Zircon, and Tourmaline. On the other hand the light minerals and the results of the mineral analyses revealed that they were primarily composed of rock fragments, with a variety of quartz minerals, feldspar minerals, evaporate minerals, clay-coated grains, and trace amounts of unidentified minerals. The abundance and diversity of heavy minerals indicate the diversity of the sources of the parent rocks, such as igneous, metamorphic and sedimentary rocks. The large amount of opaque and small amount of other minerals in the study area samples is due to the oxidation process where many of the ferromagnesian minerals such as pyroxenes, and hornblende decompose to form iron oxides (e.g. hematite, limonite). Light minerals were visible as irregular, sharp, or occasionally semi-sharp crystalline forms, which suggests that the sources were close by and that the light minerals originated from the sedimentary basin or within it through the processes of deposit erosion and re-deposition. The study area, which is a part of the Undissected Arc, is primarily distinguished by a high content of quartz (mono- and polycrystalline quartz, including chert), and feldspar, which can occur in fluvial environments.

Topaz quartzolite (greisen) in North Bohemia – potential source of the natural abrasive

Topazolite (greisen) is a rock formed essential by quartz and topaz, with accessory white mica, tourmaline, sulphides (molybdenite and arsenopyrite), wolframite and cassiterite. This rock was found in the Krkonoše and Jizera Mountains in the western Sudetes. In Poland, this metasomatic rock occurs at the contact between leucogranite and mica schist (associated with hydrothermal kaolinization) in a narrow zone between the settlements of Rebiszow and Gierałtówek. On Czech territory, similar topaz quartzolite (greisen rock), consisting of up to 65 % quartz and 32 % topaz, was found near the settlements of Růžek and Vítkov near Chrastava in association with orthogneiss. The high content of topaz in this rock offers the possibility of using it as an abrasive in high-speed abrasive water jet technology for cutting and surface treatment of hard metallic and non-metallic materials. In the crushed form, after being concentrated in a treatment plant, topaz could be a natural abrasive with a wide range of applications. However, the results of technological testing of the physical and mineralogical characteristics of the topaz concentrate indicate its unfavorable properties caused by the high fissility of topaz. This leads to losses of topaz during its technological adjustment to the required grain size or during recycling. It has been shown that abrasive concentrates with topaz content above 90 % are promising, especially for special applications of abrasive water jet technology. Mastering the technology for processing of the source raw material, i.e. topaz quartzolite, into a topaz-rich concentrate, and subsequent applied research on the use of topaz abrasives in industry are crucial.

In situ white mica Rb/Sr geochronology of the Leszczyniec metaigneous complex, West Sudetes: evidence of upper plate deformation at the onset of Variscan collision

The Karkonosze-Izera Massif in the West Sudetes preserves evidence of subduction of the Saxothuringian Ocean beneath the Teplá-Barrandian Domain. Within the massif, the Leszczyniec metaigneous complex (LMC) is identified as the upper allochthon. It exhibits a unique structural history in comparison to the underlying allochthons, suggesting that the LMC records a distinctive tectonic history. To investigate the timing of this history, two orthogneisses were studied from a single outcrop of the LMC for in situ white mica Rb/Sr geochronology. The outcrop bears a southeast-dipping foliation (S1) and a north/northeast plunging stretching lineation (L1), defined by white mica and quartz. Quartz recrystallization textures, white mica chemistry (celadonite content of 0.23–0.47), preservation of igneous plagioclase phenocrysts, and the metamorphic mineral assemblage, all indicate maximum epidote–amphibolite facies conditions. Single-spot Rb/Sr dates were calculated from white mica using initial 87Sr/86Sr values obtained by titanite and epidote. Results are similar for both rocks, providing weighted averages of 352.4 ± 4.1 Ma (MSWD: 0.6; n: 24) and 349.3 ± 2.5 Ma (MSWD: 0.4; n: 31). The rocks are interpreted to have the same structural and metamorphic history; thus, a pooled weighted average of 350.1 ± 5.3 Ma (2σ) is reported as the timing of white mica (re)crystallization during S1 and L1 development in epidote–amphibolite facies conditions. This event is bracketed by the timing of blueschist-facies metamorphism for the subjacent middle (c. 364 Ma) and lower (c. 345–341 Ma) allochthons, associated with an east/southeast-plunging L1. Considering the different structural and metamorphic histories of the LMC compared to the subjacent allochthons, it is likely that the complex was extracted from the Teplá-Barrandian upper plate due to subduction erosion prior to collective exhumation and stacking of the Karkonosze-Izera Massif.Graphical abstract

Hyperspectral mapping of magmatic-hydrothermal sericite, Battle Mountain mining district, Nevada

We demonstrate the utility of multi-scale imaging spectroscopy data (hyperspectral data) to differentiate magmatic-hydrothermal sericite from other white micas based on grain size, in a case study of the Battle Mountain mining district in Humboldt and Lander Counties, Nevada. The Battle Mountain mining district contains porphyry, skarn, and distal disseminated deposits that formed in magmatic-hydrothermal systems, as well as sedimentary-rock hosted gold deposits of less certain origin. We generated spectral-based mineral maps of the Battle Mountain mining district to examine the spatial distribution of spectrally dominant minerals such as kaolinite, montmorillonite, and white micas (muscovite, sericite, and illite). We then used spectral-based mineral mapping to characterize the grain size and composition of white micas, enabling us to differentiate igneous muscovite from magmatic-hydrothermal sericite. By integrating our spectral-based maps with geologic mapping, airborne aeromagnetic data, and prior studies on mines and deposits in Battle Mountain, we determined that finer grained, higher Al sericite spatially correlated with the footprints of known magmatic-hydrothermal systems and is interpreted as forming from magmatic-hydrothermal alteration. Larger grained, lower Al muscovites are distal from known magmatic-hydrothermal systems and are interpreted as being igneous derived siliciclastic sediments that became constituents of the host sedimentary rocks. Techniques described in this contribution can be applied to any appropriate hyperspectral data, regardless of sensor type used to collect the data.

Insights into the Subduction of the Ligure-Piemontese Oceanic Basin: New Constraints from the Metamorphism in the Internal Ligurian Units (Northern Apennines, Italy)

In the Northern Apennines, the Internal Ligurian Units are considered deformed and metamorphosed fragments of the Ligure-Piemontese oceanic basin. In this paper, we report on the temperature and pressure conditions of the metamorphic peak for four Internal Ligurian Units, estimated using different geothermometers and geobarometers based on the white mica and chlorite compositions. These minerals were formed during the D1 deformation phase in the pre-Oligocene. The results indicate that the Portello and Gottero units are both characterized by metamorphic conditions pertaining to low blueschists facies, while the Colli-Tavarone and Bracco-Val Graveglia Units show a lower metamorphic imprint that produces assemblages of prehnite-pumpellyite facies. The estimated geothermal gradient for the metamorphic peak achieved by the analyzed Internal Ligurian Units during the D1 phase is 7–15 °C/Km, which is indicative of deformation in a subduction setting. Under these conditions, the D1 phase developed in these units as a result of underplating at the base of the accretionary wedge during the closure of the Ligure-Piemontese basin. These data indicate a close geodynamic correlation among the Internal Ligurian Units and the ophiolite-bearing units of the Alps.

Interaction of surface cations of cleaved mica with water in vapor and liquid forms.

Natural minerals contain ions that become hydrated when they come into contact with water in vapor and liquid forms. Muscovite mica - a common phyllosilicate with perfect cleavage planes - is an ideal system to investigate the details of ion hydration. The cleaved mica surface is decorated by an array of K+ ions that can be easily exchanged with other ions or protons when immersed in an aqueous solution. Despite the vast interest in the atomic-scale hydration processes of these K+ ions, experimental data under controlled conditions have remained elusive. Here, atomically resolved non-contact atomic force microscopy (nc-AFM) is combined with X-ray photoelectron spectroscopy (XPS) to investigate the cation hydration upon dosing water vapor at 100 K in ultra-high vacuum (UHV). The cleaved surface is further exposed to ultra-clean liquid water at room temperature, which promotes ion mobility and partial ion-to-proton substitution. The results offer the first direct experimental views of the interaction of water with muscovite mica under UHV. The findings are in line with previous theoretical predictions.

Van der Waals Epitaxy of Bismuth‐Based Multiferroic Layered Supercell Oxide Thin Films Integrated on Flexible Mica Substrate

Bi2NiMnO6 (BNMO) epitaxial thin films with a layered supercell (LSC) structure have emerged as a promising single‐phase multiferroic material recently. Because of the required strain state for the formation of the LSC structures, most of the previous BNMO films are demonstrated on rigid oxide substrates such as SrTiO3 and LaAlO3. Here, the potential of BNMO films grown on muscovite mica substrates via van der Waals epitaxy, spotlighting their suitability for cutting‐edge flexible device applications is delved. Comprehensive scanning transmission electron microscopy/energy‐dispersive X‐ray analyses reveal a layered structure in the BNMO film and a pristine interface with the mica substrate, indicating high‐quality deposition and minimal interfacial defects. Capitalizing on its unique property of easily cleavable layers due to weak van der Waals forces in mica substrates, flexible BNMO/mica samples are fixed. A standout feature of the BNMO film grown on mica substrate is its consistent multiferroic properties across varied mechanical conditions. A novel technique is introduced for thinning the mica substrate and subsequent transfer of the sample, with post‐transfer analyses validating the preserved structural and magnetic attributes of the film. Overall, this study illuminates the resilient multiferroic properties of BNMO films on mica, offering promising avenues for their integration for next‐generation flexible electronics.

Short-wavelength infrared characteristics and composition of white mica in the Demingding porphyry Cu-Mo deposit, Gangdese belt, Tibet: Implications for mineral exploration

The Demingding Cu–Mo deposit, found in the eastern Gangdese metallogenic belt in China, has a significant exploration potential. Detailed field studies coupled with short-wavelength infrared (SWIR) spectroscopy and electron probe micro analyses (EPMA) identified a total of 15 alteration minerals such as white mica group minerals, chlorite, kandite, and smectite groups. The study also discovered the spatial distribution of alteration zone patterns, including phyllic, propylitic, and intermediate argillic alterations. Furthermore, variations were observed in the Al-OH absorption position (Pos2200) of the white mica group with variable Al-Si-Fe-Mg content. Most of the white micas in the ore zone were muscovitic series, whereas the barren zone contained phengitic series micas. Some micas have undergone a transition to illite due to low-temperature alteration overprinting. The western part of the deposit exhibited lower Pos2200, higher SWIR-IC, and higher Dep2200 values, implying an intense phyllic alteration and higher paleotemperatures. These characteristics suggest that the area is in close proximity to the hydrothermal center and fluid channel. Therefore, it was identified as an exploratory target for buried copper ore bodies. The SWIR spectra of the white mica group can be used for exploration in other similar porphyry deposits. Under acidic conditions, shorter Pos2200 and higher SWIR-IC can be used as indicators for hydrothermal or mineralization centers.